Complex Magnetic Ordering in Eu3InP3: A New Rare Earth Metal Zintl Compound

Complex magnetic ordering in Eu3InP3: a new rare earth metal zintl compound.

Eu3InP3 has been prepared as large single crystals with an indium flux reaction. The structure of the new compound is isotypic to Sr3InP3 and crystallizes in the orthorhombic space group Pnma with unit cell dimensions of a = 12.6517(15) A, b = 4.2683(5) A, and c = 13.5643(14) A (Z = 4, T = 140 K, R1 = 0.0404, wR2 = 0.0971 for all data). The structure consists of one-dimensional chains of corner...

Spin Dependent Transport and Magnetic Ordering in Rare Earth Metals

Substrate-induced magnetic ordering of rare-earth overlayers.

Rare-earth metal hydroxylamide complexes.

The rare-earth metal hydroxylamide compound Y[N(SiHMe2)2]2[ONBn2][THF] (1) was prepared by the silylamide elimination pathway from the reaction of N,N-dibenzylhydroxylamine, Bn2NOH (Bn = CH2C6H5), with Y[N(SiHMe2)2]3[THF]2 and was characterised by multinuclear NMR spectroscopy and elemental analysis. The compounds [Cp2Y(ONBn2)]2 (2a) [Cp2Sm(ONBn2)]2 (2b) were obtained by the reactions of MCp3 (...

Rare-earth metal triflates in organic synthesis.

2.1.8. Michael Reaction 2245 2.1.9. Others 2247 2.2. Cyclization Reactions 2248 2.2.1. Carbon Diels−Alder Reactions 2248 2.2.2. Aza-Diels−Alder Reactions 2252 2.2.3. Other Hetero-Diels−Alder Reactions 2255 2.2.4. Ionic Diels−Alder Reaction 2256 2.2.5. 1,3-Dipolar Cycloadditions 2256 2.2.6. Other Cycloaddition Reactions 2258 2.2.7. Prins-type Cyclization 2259 2.3. Friedel−Crafts Acylation and Al...